Nadia's major exposure has been on the soap opera Days of Our Lives, when she first appeared as the character Chloe Lane in 1999. At first, Chloe was portrayed as a nerdy and geeky kind of girl with big glasses. Eventually, her character developed into a quiet beauty who could also sing. She also developed a crush on Brady Black, portrayed by actor Kyle Lowder.
Bjorlin originally left DAYS in early 2003 to concentrate on her singing career. Her character moved to Europe to be an opera star. Bjorlin returned on a recurring basis in November 2004 after her character supposedly had a disfiguring car accident.
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